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Jafar Amiri Parian

Jafar Amiri Parian

Academic rank: Assistant Professor
ORCID:
Education: PhD.
ScopusId: 36983832100
HIndex:
Faculty: Faculty of Agriculture
Address:
Phone: 34425400

Research

Title
Acidic modification of natural stone for Remazol Black B dye adsorption from aqueous solution- central composite design (CCD) and response surface methodology (RSM)
Type
JournalPaper
Keywords
Remazol Black B (RBB), Adsorption, Pumice stone, Natural adsorbents, Response surface methodology
Year
2023
Journal Heliyon
DOI
Researchers hamed soleimani ، kiomars sharafi ، Jafar Amiri Parian ، Jalil Jaafari ، Gholamreza Ebrahimzadeh

Abstract

This study investigated the adsorption capacity of Remazol Black B (RBB) from aqueous solutions using a pumice stone as a cheap, high-frequent, and available adsorbent. The raw pumice was modified using five acids: Acetic, Sulfuric, Phosphoric, Nitric, and Hydrochloric acid. Fourier transform infrared spectrograph (FTIR), x-ray fluorescence (XRF), and scanning electron microscopy (SEM) were used to analyze the morphological and chemical properties of raw and modified adsorbents. The adsorption capacity equilibrium was investigated using the Langmuir, Freundlich, Temkin, and Dubinin – Radushkevich isotherms. The results indicated that the data are well-fitted with Langmuir isotherm. The maximum adsorption capacity was observed when pumice modified with H2SO4 (qm = 10.00 mg/g) was used, and the RBB removal efficiency was higher than that for raw pumice (qm = 5.26 mg/g). Also, the results were best fitted with pseudosecond-order kinetic. The experiments indicated that increasing the RBB concentration reduces the efficiency of adsorbents while increasing the contact time and adsorbent doses improved the RBB removal efficiency. Accordingly, it can be concluded that pumice stone modified with various acids can be considered a cheap adsorbent with high efficiency in removing RBB from industry effluent.