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Hassan Keypour

Hassan Keypour

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 55221283500 - 26643429400
HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
Address:
Phone: 08138282807

Research

Title
Synthesis and characterization of N6 macroacyclic Schiff-base ligand contaning piperazine moiety and its Mn (II) complex
Type
Presentation
Keywords
piperazine moiety
Year
2019
Researchers ، Hassan Keypour ،

Abstract

In this report we have synthesized one macroacyclic Schiff-base ligand L with the N6 donor system from condensation of 2-formylpyridine and 2,2'-(piperazine-1,4- diylbis(methylene))dianiline (A). IR spectrum of ligand exhibited a υ(C=N) vibration in 1634 cm-1. The elemental analysis, 1H and 13C NMR and the presence of a peak at 474 m/z in the mass spectrum of ligand (L) confirm the synthesis of ligand. The Mn (II) complex was synthesized by direct reaction of manganese (II) metal ion and ligand L. In the IR spectrum, υ(C=N) of the complex appears in the 1617 cm-1, and also in mass spectrum of complex the presence of peak at 728 m/z confirms the synthesis of complex. The elemental analysis confirms the synthesis of complex [1-2].