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Hassan Keypour

Hassan Keypour

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 55221283500 - 26643429400
HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
Address:
Phone: 08138282807

Research

Title
A new selective macroacyclic Schiff base fluorescent chemosensor containing homopiperazine moiety for Al3+ ion
Type
Presentation
Keywords
macroacyclic Schiff base
Year
2019
Researchers Hassan Keypour ، ، Reza azadbakht

Abstract

Al3+ ions existing in natural waters and most plants can enter the human body through foods and water. Since excess or even deficiency of aluminum ions can cause many pathological states, developing fluorescent chemosensors for detecting trace amounts of Al3+ has attracted increasing attention. a new chemosensor for Al3+ based on Schiff base with high sensitivity and selectivity was synthesized by condensation of a polyamine containing homopiperazine moiety with 2-hydroxybenzaldehyde, and characterized by IR, 1HNMR, 13CNMR and mass spectra (Scheme 1). After the addition of different metal ions such as Pb2+, Cr3+, Mn2+, Al3+, Ni2+, Co2+, Zn2+, Hg2+, Fe3+, Zn2+, Cd2+ only Al3+ could increase the fluorescence intensity of the H2L as a chemosensor (Fig.1 a). Also the fluorescence intensity of the chemosensor in ethanol