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Hassan Keypour

Hassan Keypour

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 55221283500 - 26643429400
HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
Address:
Phone: 08138282807

Research

Title
Mo(VI) complex supported on Fe3O4 nanoparticles: Magnetically separable nanocatalysts for selective oxidation of sulfides to sulfoxides
Type
JournalPaper
Keywords
molybdenum complex
Year
2015
Journal RSC Advances
DOI
Researchers Hassan Keypour ، ، Mohammad Mehdi Haghdoost ، Mojtaba Bagherzadeh

Abstract

A molybdenum complex, [MoO2Cl2(DMSO)2], was immobilized on amino propyl and Schiff base modified magnetic Fe3O4@SiO2nanoparticles by covalent linkage. The resulting nanoparticles were used as efficient and recyclable catalysts for the selective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as the oxidant. The complete characterization of catalysts was carried out by means of thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), X-ray photoelectron spectroscopy (XPS), elemental analysis, FT-IR and Raman microprobe techniques.