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Hassan Keypour

Hassan Keypour

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 55221283500 - 26643429400
HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
Address:
Phone: 08138282807

Research

Title
Hydrogenation of benzene in gasoline fuel over nanoparticles (Ni, Pt, Pd, Ru and Rh) supported fullerene: Comparison study
Type
Presentation
Keywords
supported fullerene
Year
2014
Researchers Hassan Keypour ، ، Alimorad Rashidi

Abstract

The main purpose of the present study is to synthesis different fullerene (C60)-based metal nanocatalysts that is used for the catalytic hydrogenation of benzene in gasoline. In this paper, the fullerenes are used as a support medium for metal catalysts[1-3]. A new method (involves a combination of impregnation, ultrasound and reduction methods) was used to produce these catalysts and fullerenol was synthesized by using oleum (H2SO4 SO3), followed by the hydrolysis of the intermediate cyclosulfated fullerene an oxidizing agent was employed to functionalize the fullerenes[4]. Catalytic activity was evaluated over a temperature range 25 250 ºC under a hydrogen pressure range 1-50 atm, metal content of catalyst ranging from 1-10% (w/w) and reaction time of 30-180 min. The results show that the yield of hydrogenation under optimum conditions (metal loading of about 10%, reaction time of 180 min and pressure of 50 atm) are obtained: 99.59, 99.48, 98.09, 98.51 and 97.56%, for Rh, Ru, Pt, Pd and Ni, respectively.