مشخصات پژوهش

صفحه نخست /Synthesis of Nitroolefins and ...
عنوان
Synthesis of Nitroolefins and Nitroarenes under Mild Conditions
نوع پژوهش مقاله چاپ‌شده
کلیدواژه‌ها
1,3-Disulfonic acid imidazolium nitrate
چکیده
1,3-Disulfonic acid imidazolium nitrate {[Dsim]NO3} was prepared and characterized as a new ionic liquid and nitrating agent for the ipso-nitration of various arylboronic acids and nitro-Hunsdiecker reaction of different α,β-unsaturated acids and benzoic acid derivatives, by in situ generation of NO2 to give various nitroarenes and nitroolefins without using any cocatalysts and solvents under mild conditions.
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